In modern pulp and paper mills, nearly all key
equipment (digesters, bleaching systems, evaporators, storage tanks and paper
machines) are made from various types of stainless steels. Approximately 5,000
to 6,000 tonnes of stainless steel go into a large new pulp and paper mill. On
top of that, there is piping, welding consumables and auxiliary equipment. The
materials used are standard austenitic, duplex and high-alloy super-austenitic
stainless steels.
Currently, the high price of the alloying elements in
the raw materials is one of the reasons why manufacturers serving the pulp and
paper industry are showing increased interest in duplex steels. However, the most
important factor is that, even though the nickel and molybdenum content is generally
low, duplex steels have very good properties. Previously, so-called acid-resistant
steels were used when the sulphite process (an acid process) was used in cooking
paper pulp. Now that the industry is increasingly switching to sulphate or other
alkaline solutions, such steels are no longer optimal, says Lena Wegrelius.
Stress
corrosion presents the greatest risk in alkaline
cooking and stainless steels with a high
chromium content, low molybdenum content and duplex microstructure are
optimal for these environments. Furthermore, the strength of duplex steels is
"twice" that of standard steels. Consequently this allows pressure vessels
to be built with thinner walls. Duplex steels are more cost-efficient austenitic
steels.
Duplex stainless steel are becoming ever more popular with
equipment manufacturers. Avesta has a new duplex grade, LDX 2101®, which is
excellent for the paper industry. However, its a fact that the choice of materials
when building new plants or machinery is not determined solely by what is best
for the application. For example, in Latin America, mills are favoring their own
local producers and these producers do not always manufacture duplex steel. In
those cases, standard materials are being used. Its believed that Chinese manufacturers
will soon be producing duplex steels themselves.
Failure
of a super duplex stainless steel reaction vesselV.
M. LintonCorresponding Author Contact Information, E-mail The Corresponding Author,
a, N. J. Laycockb, S. J. Thomsenb and A. Klumpersb a University of Adelaide,
Adelaide, 5005, South, Australia b Materials Performance Technologies, Industrial
Research Ltd, Lower Hutt, New Zealand Received 1 July 2002; Available online
18 November 2003. Abstract Crevice
corrosion and stress corrosion cracking (SCC) were recently discovered in a vessel
used to strip vinyl chloride monomer from a water-based slurry of PVC granules.
The vessel was manufactured from UNS S32750 super duplex
stainless steel and the welds were produced using matching welding consumables.
Although localised corrosion might have been expected, the occurrence
of SCC was inconsistent with the majority of the published literature: in particular,
the nominal operating temperature should have been too low for chloride-induced
SCC of super-duplex stainless steel. However, damage was found mainly in the vicinity
of the circumferential and longitudinal welds, and part
of the subsequent failure investigation was therefore focused on the possibility
of poor weld quality being the cause of failure.
This task was
approached primarily by measuring the influence of welding
parameters on the value of the critical pitting temperature (CPT), and
attempting to correlate the results with observed changes in the weld microstructure.
CPT values were determined by a potentiodynamic method, using samples cut from
the failed vessel and from a range of reference welds manufactured using known
welding parameters.
|
At
Smurfit Kappa Kraftliner, Piteå, both the peroxide reactor and the oxygen
reactor, behind it, are manufactured from 2205 duplex stainless steel.

From
Avesta: The commercial development of stainless steel occurred side by side with
that of the modern pulp and paper industry. This was a phenomenon of 1940s
northern Europe. The unique collaborations between engineering companies (developers
of new and more efficient pulp and paper processes) and steel mills have led to
unsurpassed expertise in stainless steels for various pulp and paper applications.
They have also led to the development of new steel grades such as 254 SMO®
and LDX 2101®. To test how its steel grades stand up to various environments,
Outokumpu has a number of research and development collaborations with mills,
machine builders, research institutes and engineering companies. Amongst other
projects, Lena Wegrelius mentions that with an inspection company, Inspecta. In
this, field tests are being run in digester and evaporator environments at the
Smurfit Kappa Kraftliner pulp and paper mill in Piteå. We are also
working with Chempolis Oy in Finland. The latter company is looking at processes
for cooking pulp from raw materials other than wood. This is of future interest
for the Asian market, she declares. In China, for example, trials are being
conducted with the common reed and residual products from arable and rice farming.
New processes and steel grades may be necessary here. What else can be said about
developments in pulp and paper? For environmental reasons, the industry
is using more and more recycled paper in its raw materials. It is often said that
fibres can be used seven times before they are finished. Recycling processes are
thus becoming increasingly more important in pulp production, concludes
Lena Wegrelius.
AVESTA
NEW DUPLEX FLUX CORED WIRE: Avesta FCW-2D LDX 2101There is now a new and
improved version of Avesta Weldings flux cored wire for welding Outokumpus
new duplex steel, the LDX 2101®.Avesta FCW-2D LDX 2101 gives a duplex weld
metal that combines excellent mechanical properties with good corrosion resistance.
In both the flat and the horizontal-vertical (PC) positions, weldability is very
good Positive direct current (DC+) is used for welding flux cored wires. Compared
with MIG welding, the flux cored wire parameter range is considerably wider. Avesta
FCW-2D is an 0.045 1.2 mm wire supplied in a layer wound on 15-kilo wire basket
spools. Avesta Weldings range of filler metals for welding LDX 2101®
also includes covered electrodes and solid MIG, TIG and SAW wires.
AVESTA
2304
For welding storage tanks, recovery boiler
pipes, oxygen reactors, etc. in duplex stainless steel 2304 (EN 1.4362, Outokumpu
2304). Avesta Welding is the first supplier in the
world able to offer a complete
range of matching filler metals for this duplex grade. The range comprises covered
electrodes, flux cored wires and solid wires (MIG/TIG/SAW).
AVESTA
2205
For welding batch and continuous digesters,
oxygen delignification and pressurized peroxide reactors, press washers, pulp
towers and filters, etc. made of 2205 duplex stainless
steel (EN 1.4462, Outokumpu
2205). Giving excellent mechanical properties and corrosion resistance, Avesta
2205 has a long record of success in these applications.
AVESTA
2507/P100
For welding super duplex 2507 (EN 1.4410,
Outokumpu SAF 2507) and similar grades. Avestas 2507/P100 range of highly
alloyed super duplex consumables provides better
strength and corrosion resistance
than ordinary duplex fillers.
AVESTA
LDX 2101
Specially designed for welding Outokumpu
LDX 2101 (EN 1.4162), the new high-strength low-alloy duplex stainless steel.
Thanks to its superior strength and good corrosion resistance in alkaline environments,
this cost-efficient material is a maintenance-free option for railings, walkways,
storage tanks and even hydrogen peroxide reactors in pulp bleaching.
With Avesta
LDX 2101, it is easy to achieve a sound weld that, as regards corrosion resistance
and mechanical properties,
matches the parent metal.
130
ton Brazilian urea reactor.
Jaraguá of Brazil manufactured
and delivered a complete urea reactor to Petrobras/FAFEN in Camaçari (Brazil),
all the stainless steel plates and welding consumables came from, respectively,
Outokumpu and Avesta Welding in Sweden. The reactor, which was the first to be
produced in South America, weighs 130 tonnes. Besides conventional non-destructive
testing, the reactor was subjected to helium leakage tests and positive material
identification (PMI). Furthermore, all stainless steel (welded joints included
therein) were corrosion tested as per ASTM A262s practice C
(Huey test). The special technique developed to measure the gap between shell
and lining (maximum permitted limit of 3.0 mm) is worthy of individual highlighting.
Compared with other assignments, one of the greatest differences for Jaraguá
was that, to guarantee perfect handling and cleaning of the stainless steel, manufacture
of the reactor was kept entirely separate from other production.
Realisation
and testing was in accordance with ASME Code Section IX. In addition, test coupons
for the qualification of welding procedures were tested as follows:
Article
From Avesta.
Note from Ed This company
and Sanvik are an excellent source for duplex info.
High
productivity welding of the new lean duplex stainless steel,
LDX 2101® (S32101)
With their strengthening in the
mid 1980's, duplex steels increasingly provided an alternative to conventional
austenitic steels. They were then predominantly used for chemical tankers as well
as process vessels and storage tanks in the pulp and paper industry. It is the
good combination of strength and corrosion resistance that makes duplex stainless
steels so attractive. However, in the beginning, the duplex grades were primarily
seen as alternatives to high-performance austenitic grades (e.g. 904L and 254
SMO®) rather than as alternatives to conventional grades (e.g. 304 and 316).
This limited their use in general construction. Here, high strength is needed
rather than high corrosion resistance. Developed by Outokumpu Stainless, LDX 2101®,
the new "lean" duplex stainless steel, is now used in a very wide range
of applications.
General
purpose and structural applications are just two examples. The high strength
and good corrosion resistance of LDX 2101® also make it extremely suitable
for a variety of
storage tanks. This article focuses on examining how high
productivity welding methods using Avesta LDX 2101, can be optimised to maximise
the good corrosion resistance and mechanical properties of duplex LDX 2101 stainless
steel. Strength and corrosion resistance Of the duplex grades currently on the
market, LDX 2101® has the "least alloyed" chemical composition with
a nickel content of just 1.5% (balanced with 5% manganese and some 0.22% nitrogen),
LDX 2101 offers high mechanical strength and corrosion resistance at an advantageous
price. Nickel is an expensive metal. Furthermore, its price fluctuates widely
over time. This can present major difficulties when estimating the total cost
of a construction.The chemical composition of LDX 2101 is balanced to give a microstructure
with approximately equal amounts of ferrite and austenite. Thanks to the high
nitrogen content, austenite re-formation after welding is rapid. In general, corrosion
properties are as good as, or better than, those of the Cr-Ni grade EN 1.4301/
AISI 304. Furthermore, the steel's duplex structure and high nitrogen content
result in a mechanical strength almost twice that of ordinary, austenitic steels.
The
high strength of LDX 2101 steel can be used to optimise the design of various
storage tanks. On top of this, the steel's cost efficiency can be fully exploited
by selecting the correct filler (Avesta LDX 2101) and welding method.Better properties
with matching filler metals Because it is optimised to ensure the best welding
characteristics and mechanical properties, the matching Avesta LDX 2101 filler
should be used to weld LDX 2101® duplex stainless steel. To obtain a suitable
ferrite/austenite balance in the weld metal, Avesta LDX 2101 is over-alloyed with
nickel.
The microstructure of metal arc welded LDX 2101 has a typical
duplex appearance with 30 - 65% ferrite.Testing of LDX 2101 welds has shown that
tensile strength is higher than 680 MPa / 99 ksi and that fracture most commonly
occurs in the parent metal. Bending tests to 180°
with a 3 x t mandrel
have shown no signs of cracking.
Duplex Welding
Methods and Weldability. Excellent results are obtained when welding LDX
2101 using all conventionalmethods - SMAW, FCAW, MIG, TIG and SAW. General recommendations
for the welding of storage tanks are given below.
Duplex
FCAW: Widely used for all types
of welding, both workshop and on-site.Suitable plate thicknesses are 5 mm (0.20")
and upwards. FCAW gives high productivity in all positions. The shielding gas
can be either Ar + 20 - 25% CO2 or 100% CO2. Welding is mainly in the flat and
horizontal-vertical positions. FCAW is often combined with SMAW and Pulsed MIG:
Especially if it can be carried out against a backing strip, or with overlap joints.
Duplex
MIG, welding is an economical method that is well suited to continuous
welding of small thin-walled tanks (2 - 6 mm / 0.08 - 0.23"). MIG Welding
is best performed with pulsed MIG transfer. For gas selection see Ed's recommendations
in the MIG gas section.
SMAW:
Because of its excellent flexibility in all positions, SMAW is suitable
for on-site vertical-up welding, tacking and repair welding (in all positions).
Avesta LDX 2101(a rutile-acid electrode) gives a stable arc, good slag removal
and, in fillet welds, a concave, smooth weld reinforcement. Note first choice,
gas shielded flux cored. if wire available.
SAW:
This method is mostly used for welding thick sections of sheet metals >12 mm
(0.47") and upwards. To avoid excessive fusion of the parent metal, 2.4 mm
(3/32") diameter wire and V, U and X-joints are recommended. A basic flux
(Avesta Flux 805) should be used for welding. The root bead can advantageously
be welded using another high productivity method such as MIG or FCAW. Heat input
should not exceed 1.5 kJ/mm (38 kJ/inch) especially where the structure is used
in a low temperature environment. Too high a degree of parent metalfusion can
lower impact strength.
Another
great source of Duplex
Weld Data / Electrodes is
Sanvik / ESAB.

July
2008. Sandvik Materials Technology has launched a hyper duplex stainless steel
tube material which is designed to improve umbilical performance in increasingly
demanding subsea environments. Sandvik SAF 3207 HD is
designed specifically for deepwater, high temperature, and extreme pressure applications.
Sandvik SAF 3207 HD provides a tensile strength
of 980 to 1180MPa and a maximum operating temperature of up to 90C. This compares
with a tensile strength of 800-1100MPa and maximum water temperature rating of
65C for the companys standard super-duplex grade SAF 2507. SAF 2507 can
be deployed in water depths greater than 2000m. However, as the pressure at the
seabed increases with depth, the wall thickness of the tube eventually becomes
so great that it can become uneconomical to purchase all the material required.
Duplex
steels offer great mechanical properties and corrosion resistance. The primary
difference between austenitic stainless and duplex steels is the duplex offers
a balanced microstructure of approx. equivalent volumes of both ferrite and austenite.
Typically the duplex steel will have a weld ferrite content of 40 to 60% and the
weld 25 to 40 % ferrite. A 25% to 50% ferrite range
is desirable.
In
comparison to traditional austenitic stainless, the duplex, two-phase microstructure
and high chrome / Mo can result in duplex applications that have; [a]
higher resistance to stresses,
[b] higher resistance to pitting corrosion
cracking,
[c] improved intergranular corrosion resistance.
Note:
Be aware of too much or too little ferrite. Rapid quenching
of the duplex weld as found in arc strikes or small welds on large parts
should be avoided as this can result in very high ferrite content > 60%. The
extra high ferrite welds can result in low toughness or low corrosion resistance.
Ferrite in duplex results in lower coefficient of thermal expansion in
contrast to austenitic stainless resulting in less weld distortion potential.
The
Metallurgy of Duplex Stainless Steels.
Most
duplex have an alloy range of,
Cr - 22 to 26%.
Ni - 4 to 7%.
Mo
- 0 to 3%.
With 0.1 to 0.3 Nitrogen, (no nitrogen will be in filler metals)
Nitrogen
plays an important role of present day duplex alloys. Nitrogen is a potent austenite
stabilizer. The addition of nitrogen to the duplex steel will promote structural
hardening by a solid solution mechanism. The nitrogen therefore will raise both
the yield strength and ultimate strengths of the duplex without impairing toughness.
Nitrogen cannot be added to the filler metal as
it can not transfer across the arc. When welding nitrogen can be added to the
weld through the shielding or purge gas.